The Crystal Structure of trans-[{Rh(μ-Cl)(CO)(coe)}2] (coe = cis-cyclooctene)
نویسندگان
چکیده
The synthesis of trans-[{Rh(μ-Cl)(CO)(coe)}2] (1) was described by Varshavsky et al. some years ago [1, 2], but no crystal structure of this compound was reported. In an attempt to probe a possible convenient synthesis of [{Rh(μ-Cl)(CO)2}2] from the precursor [{Rh(μ-Cl)(coe)2}2] and carbon monoxide in diethyl ether, we found that the target complex was not available by this method. Instead, the title compound 1 was obtained in high yield. We report here its molecular structure and its characterization by NMR spectroscopy.
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